REACH規則 制限対象物質の追加(Entry 72)
2019.1.20 update
2019.1.20 制限対象物質の追加に気づくのが遅れました。申し訳ありません。
制限対象物質の追加
2018年10月10日、欧州委員会は衣料品、履き物、繊維製品にCMR33物質（発がん性、変異原性、生殖毒性のカテゴリー１Ａ、１Ｂの物質）の使用を制限することを発表しました。衣料品や繊維製品にCMR物質の最大濃度を設定し、生産地にかかわらずEU市場でこの制限を超える製品を禁止します。
CMR33物質は制限対象物質のEntry72に追加します。
制限条件
Entry 72
The following substances which are classified as carcinogenic, mutagenic or toxic for reproduction, category 1A or 1B (See group members)
The substances listed in column 1 of the Table in Appendix 12
Appendix 12
Entry 72 — restricted substances and maximum concentration limits by weight in homogeneous materials:
| Substances | 物質名(日本語参考訳） | CAS No. | Concentration limit by weight | |
|---|---|---|---|---|
| 1 | Cadmium and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6) | カドミウムおよびその化合物(Annex XVII, Entry 28, 29, 30, Appendices 1-6) | － | 1mg/kg after extraction (expressed as Cd metal that can be extracted from the material) |
| 2 | Chromium VI compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6) | ６価クロム化合物(Annex XVII, Entry 28, 29, 30, Appendices 1-6) | － | 1mg/kg after extraction (expressed as Cr VI that can be extracted from the material) |
| 3 | Arsenic compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6) | ヒ素化合物(Annex XVII, Entry 28, 29, 30, Appendices 1-6) | － | 1mg/kg after extraction (expressed as As metal that can be extracted from the material) |
| 4 | Lead and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6) | 鉛およびその化合物(Annex XVII, Entry 28, 29, 30, Appendices 1-6) | － | 1mg/kg after extraction (expressed as Pb metal that can be extracted from the material) |
| 5 | Benzene | ベンゼン | 71-43-2 | 5mg/kg |
| 6 | Benz[a]anthracene | ベンゾ[a]アントラセン | 56-55-3 | 1mg/kg |
| 7 | Benz[e]acephenanthrylene | ベンゾ[e]アセフェナントリレン | 205-99-2 | 1mg/kg |
| 8 | benzo[a]pyrene; benzo[def]chrysene | ベンゾ[a]ピレン; ベンゾ[def]クリセン | 50-32-8 | 1mg/kg |
| 9 | Benzo[e]pyrene | ベンゾ[e]ピレン | 192-97-2 | 1mg/kg |
| 10 | Benzo[j]fluoranthene | ベンゾ[j]フルオラテン | 205-82-3 | 1mg/kg |
| 11 | Benzo[k]fluoranthene | ベンゾ[k]フルオラテン | 207-08-9 | 1mg/kg |
| 12 | Chrysene | クリセン | 218-01-9 | 1mg/kg |
| 13 | Dibenz[a,h]anthracene | ジベンゾ[a,h]アントラセン | 53-70-3 | 1mg/kg |
| 14 | α, α,α,4-tetrachlorotoluene; p-chlorobenzotrichloride | α, α,α,4-テトラクロロトルエン; p-クロロベンゾトリクロライド | 5216-25-1 | 1mg/kg |
| 15 | α, α,α-trichlorotoluene; benzotrichloride | α, α,α-トリクロロトルエン; ベンゾトリクロライド | 98-07-7 | 1mg/kg |
| 16 | α-chlorotoluene; benzyl chloride | α-クロロトルエン; ベンジルクロライド | 100-44-7 | 1mg/kg |
| 17 | Formaldehyde | ホルムアルデヒド | 50-00-0 | 75mg/kg |
| 18 | 1,2-benzenedicarboxylic acid; di-C 6-8-branched alkylesters, C 7-rich | フタル酸ジ分岐アルキルエステル(炭素数6～8、7が主成分） | 71888-89-6 | 1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
| 19 | Bis(2-methoxyethyl) phthalate | フタル酸ビス（2-メトキシエチル） | 117-82-8 | 1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
| 20 | Diisopentylphthalate | フタル酸ジイソペンチル | 605-50-5 | 1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
| 21 | Di-n-pentyl phthalate (DPP) | フタル酸ジ-n-ペンチル（DPP) | 131-18-0 | 1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
| 22 | Di-n-hexyl phthalate (DnHP) | フタル酸ジ-n-へキシル | 84-75-3 | 1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B |
| 23 | N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone (NMP) | N-メチル-2-ピロリドン、1-メチル-2-ピロリドン | 872-50-4 | 3000 mg/kg |
| 24 | N,N-dimethylacetamide (DMAC) | N,N-ジメチルアセトアミド(DMAC) | 127-19-5 | 3000 mg/kg |
| 25 | N,N-dimethylformamide; dimethyl formamide (DMF) | N,N-ジメチルホルムアミド、ジメチルホルムアミド(DMF) | 68-12-2 | 3000 mg/kg |
| 26 | 1,4,5,8-tetraaminoanthraquinone; C.I. Disperse Blue 1 | 1,4,5,8-テトラアミノアントラキノン、C.I.ディスパースブルー１ | 2475-45-8 | 50mg/kg |
| 27 | Benzenamine, 4,4′-(4-iminocyclohexa-2,5- dienylidenemethylene)dianiline hydrochloride; C.I. Basic Red 9 | 4,4'-(4-イミノシクロヘキサ-2,5-ジエニリデンメチル）ジアニリン塩酸塩 | 569-61-9 | 50mg/kg |
| 28 | [4-[4,4'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride; C.I. Basic Violet 3 with ≧0,1% of Michler's ketone ((EC No. 202-027-5) | [4-[4,4'-ビス(ジメチルアミノ)ベンズヒドリデン]シクロヘキサ-2,5-ジエン-1-イリデン］ジメチルアンモニウムクロリド(C.I. ベーシックバイオレット3）（ミヒラーズケトン(EC No. 202-027-5)またはミヒラーズベース（EC No. 202-959-2）を0.1%以上含んでいる場合） | 548-62-9 | 50 mg/kg |
| 29 | 4-chloro-o-toluidinium chloride | 4-クロロ-o-トルイジン塩酸塩 | 3165-93-3 | 30 mg/kg |
| 30 | 2-Naphthylammoniumacetate | 2-ナフタレンアミン酢酸塩 | 553-00-4 | 30 mg/kg |
| 31 | 4-methoxy-m-phenylene diammonium sulphate; 2,4-diaminoanisole sulphate | 4-メトキシ-m-フェニレンジアンモニウム硫酸塩、2,4-ジアミノアニソール硫酸塩 | 39156-41-7 | 30 mg/kg |
| 32 | 2,4,5-trimethylaniline hydrochloride | 2,4,5-トリメチルアニリン塩酸塩 | 21436-97-5 | 30 mg/kg |
| 33 | Quinoline | キノリン | 91-22-5 | 50 mg/kg |
Conditions of restriction
1. Shall not be placed on the market after 1 November 2020 in any of the following:
(a) clothing or related accessories;
(b) textiles other than clothing which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to an extent similar to clothing;
(c) footwear;
if the clothing, related accessory, textile other than clothing or footwear is for use by consumers and the substance is present in a concentration, measured in homogeneous material, equal to or greater than that specified for that substance in Appendix 12.
2. By way of derogation, in relation to the placing on the market of formaldehyde [CAS No 50-00-0] in jackets, coats or upholstery, the relevant concentration for the purposes of paragraph 1 shall be 300 mg/kg during the period between 1 November 2020 and 1 November 2023. The concentration specified in Appendix 12 shall apply thereafter.
3. Paragraph 1 shall not apply to:
(a) clothing, related accessories or footwear, or parts of clothing, related accessories or footwear, made exclusively of natural leather, fur or hide;
(b) non-textile fasteners and non-textile decorative attachments;
(c) second-hand clothing, related accessories, textiles other than clothing or footwear
(d) wall-to-wall carpets and textile floor coverings for indoor use, rugs and runners.
4. Paragraph 1 shall not apply to clothing, related accessories, textiles other than clothing, or footwear within the scope of Regulation (EU) 2016/425 of the European Parliament and of the Council1 or Regulation (EU) 2017/745 of the European Parliament and of the Council2.
5. Paragraph 1(b) shall not apply to disposable textiles. ‘Disposable textiles’ means textiles that are designed to be used only once or for a limited time and are not intended for subsequent use for the same or a similar purpose.
6. Paragraphs 1 and 2 shall apply without prejudice to the application of any stricter restrictions set out in this Annex or in other applicable Union legislation.
7.The Commission shall review the exemption in paragraph 3(d) and, if appropriate, modify that point accordingly.
参考