化学物質管理の情報サイト

Entry 11

Volatile esters of bromoacetic acids:　
揮発性ブロモ酢酸エステル類

 

(a) Methyl bromoacetate　
　　ブロモ酢酸メチル
　　CAS No 96-32-2, EC No 202-499-2
(b) Ethyl bromoacetate 　
　　ブロモ酢酸エチル
　　CAS No 105-36-2, EC No 203-290-9
(c) Propyl bromoacetate　
　　ブロモ酢酸プロピル
　　CAS No 35223-80-4
(d) Butyl bromoacetate　
　　ブロモ酢酸ブチル
　　CAS No 18991-98-5, EC No 242-729-9

 

Conditions of restriction

1. Shall not be used, in jokes and hoaxes or in mixtures or articles intended to be used as such, for instance as a constituent of sneezing powder and stink bombs.

 

2. Jokes and hoaxes, or mixtures or articles intended to be used as such, not complying with paragraph 1 shall not be placed on the market.

 

3. However, paragraphs 1 and 2 shall not apply to stink bombs containing not more than 1,5 ml of liquid.

Entry 12

2-Naphthylamine and its salts
2-ナフチルアミンおよびその塩

 

CAS No 91-59-8, EC No 202-080-4

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures in concentrations greater than 0,1 % by weight.

Entry 13

Benzidine and its salts
ベンジジンおよびその塩

 

CAS No 92-87-5, EC No 202-199-1

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures in concentrations greater than 0,1 % by weight.

Entry 14

4-Nitrobiphenyl
4-ニトロビフェニル

 

CAS No 92-93-3, EC No 202-204-7

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures in concentrations greater than 0,1 % by weight.

 

Entry 15

4-Aminobiphenyl xenylamine and its salts
4-アミノビフェニルおよびその塩

 

CAS No 92-67-1, EC No 202-177-1

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures in concentrations greater than 0,1 % by weight.

 

Entry 16

Lead carbonates:
炭酸鉛（Ⅱ）

 

(a) Neutral anhydrous carbonate (PbCO3)
　　中性炭酸鉛
　　CAS No 598-63-0, EC No 209-943-4

 

(b) Trilead-bis(carbonate)-dihydroxide 2PbCO3-Pb(OH)2
　　塩基性炭酸鉛
　　CAS No 1319-46-6, EC No 215-290-6

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.

 

However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof.

Entry 17

Lead sulphates:
硫酸鉛

 

(a) PbSO4
　　硫酸鉛(Ⅱ)
　　CAS No 7446-14-2, EC No 231-198-9
(b) PbxSO4
　　硫酸鉛
　　CAS No 15739-80-7, EC No 239-831-0

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.

 

However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof.

Entry 18

Mercury compounds
水銀化合物

 

Conditions of restriction

Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use:

 

(a) to prevent the fouling by micro-organisms, plants or animals of:
— the hulls of boats,
— cages, floats, nets and any other appliances or equipment used for fish or shellfish farming,
— any totally or partly submerged appliances or equipment;

 

(b) in the preservation of wood;

 

(c) in the impregnation of heavy-duty industrial textiles and yarn intended for their manufacture;

 

(d) in the treatment of industrial waters, irrespective of their use.

Entry 18a

Mercury
水銀

 

CAS No 7439-97-6, EC No 231-106-7

 

Conditions of restriction

1. Shall not be placed on the market:
(a) in fever thermometers;
(b) in other measuring devices intended for sale to the general public (such as manometers, barometers, sphygmomanometers, thermometers other than fever thermometers).

 

2. The restriction in paragraph 1 shall not apply to measuring devices that were in use in the Community before 3 April 2009. However Member States may restrict or prohibit the placing on the market of such measuring devices.

 

3. The restriction in paragraph 1(b) shall not apply to:
(a) measuring devices more than 50 years old on 3 October 2007;
(b) barometers (except barometers within point (a)) until 3 October 2009.

 

(4. Regulation (EU) No 847/2012: paragraph 4 is deleted).

 

5. The following mercury-containing measuring devices intended for industrial and
professional uses shall not be placed on the market after 10 April 2014:
(a) barometers;
(b) hygrometers;
(c) manometers;
(d) sphygmomanometers;
(e) strain gauges to be used with plethysmographs;
(f) tensiometers;
(g) thermometers and other non-electrical thermometric applications.
The restriction shall also apply to measuring devices under points (a) to (g) which are placed on the market empty if intended to be filled with mercury.

 

6. The restriction in paragraph 5 shall not apply to:
(a) sphygmomanometers to be used:
　(i) in epidemiological studies which are ongoing on 10 October 2012;
　(ii) as reference standards in clinical validation studies of mercury-free sphygmomanometers;

 

(b) thermometers exclusively intended to perform tests according to standards that require the use of mercury thermometers until 10 October 2017;

 

(c) mercury triple point cells which are used for the calibration of platinum resistance thermometers.

 

 

7. The following mercury-using measuring devices intended for professional and industrial uses shall not be placed on the market after 10 April 2014:
(a) mercury pycnometers;
(b) mercury metering devices for determination of the softening point.

 

8. The restrictions in paragraphs 5 and 7 shall not apply to:
(a) measuring devices more than 50 years old on 3 October 2007;
(b) measuring devices which are to be displayed in public exhibitions for cultural and historical purposes.

Entry 19

Arsenic compounds
ヒ素化合物

 

Conditions of restriction

1. Shall not be placed on the market, or used, as substances or in mixtures where the
substance or mixture is intended for use to prevent the fouling by micro-organisms, plants or animals of:
— the hulls of boats,
— cages, floats, nets and any other appliances or equipment used for fish or shellfish farming,
— any totally or partly submerged appliances or equipment.

 

2. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use in the treatment of industrial waters, irrespective of their use.

 

3. Shall not be used in the preservation of wood. Furthermore, wood so treated shall not be placed on the market.

 

4. By way of derogation from paragraph 3:
(a) Relating to the substances and mixtures for the preservation of wood: these may only be used in industrial installations using vacuum or pressure to impregnate wood if they are solutions of inorganic compounds of the copper, chromium, arsenic (CCA) type C and if they are authorised in accordance with Article 5(1) of Directive 98/8/EC.
Wood so treated shall not be placed on the market before fixation of the preservative is completed.

 

(b) Wood treated with CCA solution in accordance with point (a) may be placed on the market for professional and industrial use provided that the structural integrity of the wood is required for human or livestock safety and skin contact by the general public during its service life is unlikely:
— as structural timber in public and agricultural buildings, office buildings, and industrial premises,
— in bridges and bridgework,
— as constructional timber in freshwater areas and brackish waters, for example jetties and bridges,
— as noise barriers,
— in avalanche control,
— in highway safety fencing and barriers,
— as debarked round conifer livestock fence posts,
— in earth retaining structures,
— as electric power transmission and telecommunications poles,
— as underground railway sleepers.

 

(c) Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that all treated wood placed on the market is individually labelled ‘For professional and industrial installation and use only, contains arsenic’. In addition, all wood placed on the market in packs shall also bear a label stating ‘Wear gloves when handling this wood. Wear a dust mask and eye protection when cutting or otherwise crafting this wood. Waste from this wood shall be treated as hazardous by an authorised undertaking’.

 

(d) Treated wood referred to under point (a) shall not be used:
— in residential or domestic constructions, whatever the purpose,
— in any application where there is a risk of repeated skin contact,
— in marine waters,
— for agricultural purposes other than for livestock fence posts and structural uses in accordance with point (b),
— in any application where the treated wood may come into contact with intermediate or finished products intended for human and/or animal
consumption.

 

5. Wood treated with arsenic compounds that was in use in the Community before 30 September 2007, or that was placed on the market in accordance with paragraph 4 may remain in place and continue to be used until it reaches the end of its service life.

 

6. Wood treated with CCA type C that was in use in the Community before 30 September 2007, or that was placed on the market in accordance with paragraph 4:
— may be used or reused subject to the conditions pertaining to its use listed under points 4(b), (c) and (d),
— may be placed on the market subject to the conditions pertaining to its use listed
under points 4(b), (c) and (d).

 

7. Member States may allow wood treated with other types of CCA solutions that was in use in the Community before 30 September 2007:
— to be used or reused subject to the conditions pertaining to its use listed under points 4 (b), (c) and (d),
— to be placed on the market subject to the conditions pertaining to its use listed under points 4(b), (c) and (d).

Entry 20

Organostannic compounds
有機スズ化合物

Conditions of restriction

1. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is acting as biocide in free association paint.

 

2. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture acts as biocide to prevent the fouling by micro-organisms, plants or animals of:

 

(a) all craft irrespective of their length intended for use in marine, coastal, estuarine and inland waterways and lakes;
(b) cages, floats, nets and any other appliances or equipment used for fish or shellfish farming;
(c) any totally or partly submerged appliance or equipment.

 

 

3. Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use in the treatment of industrial waters.

 

4. Tri-substituted organostannic compounds:

 

(a) Tri-substituted organostannic compounds such as tributyltin (TBT) compounds and triphenyltin (TPT) compounds shall not be used after 1 July 2010 in articles where the concentration in the article, or part thereof, is greater than the equivalent of 0,1 % by weight of tin.

 

(b) Articles not complying with point (a) shall not be placed on the market after 1 July 2010, except for articles that were already in use in the Community before that date.

 

 

5. Dibutyltin (DBT) compounds:
(a) Dibutyltin (DBT) compounds shall not be used after 1 January 2012 in mixtures and articles for supply to the general public where the concentration in the mixture or the article, or part thereof, is greater than the equivalent of 0,1 % by weight of tin.

 

(b) Articles and mixtures not complying with point (a) shall not be placed on the market after 1 January 2012, except for articles that were already in use in the Community before that date.

 

(c) By way of derogation, points (a) and (b) shall not apply until 1 January 2015 to the following articles and mixtures for supply to the general public:

 

— one-component and two-component room temperature vulcanisation sealants (RTV-1 and RTV-2 sealants) and adhesives,
— paints and coatings containing DBT compounds as catalysts when applied on articles,
— soft polyvinyl chloride (PVC) profiles whether by themselves or coextruded with hard PVC,
— fabrics coated with PVC containing DBT compounds as stabilisers when intended for outdoor applications,
— outdoor rainwater pipes, gutters and fittings, as well as covering material for roofing and façades,

 

(d) By way of derogation, points (a) and (b) shall not apply to materials and articles regulated under Regulation (EC) No 1935/2004.

 

6. Dioctyltin (DOT) compounds:
(a) Dioctyltin (DOT) compounds shall not be used after 1 January 2012 in the following articles for supply to, or use by, the general public, where the concentration in the article, or part thereof, is greater than the equivalent of 0,1 % by weight of tin:
— textile articles intended to come into contact with the skin,
— gloves,
— footwear or part of footwear intended to come into contact with the skin,
— wall and floor coverings,
— childcare articles,
— female hygiene products,
— nappies,
— two-component room temperature vulcanisation moulding kits (RTV-2 moulding kits).

 

(b) Articles not complying with point (a) shall not be placed on the market after 1 January 2012, except for articles that were already in use in the Community before that date.